STUDY ON THE EFFECT OF THE INTERMOLECULAR FORCE TO THE CAPACITY RATIOIN HPLC BY SCALED PARTICLE THEORY

Authors
ZHANG WB SHI JJ
Citation
Wb. Zhang et Jj. Shi, STUDY ON THE EFFECT OF THE INTERMOLECULAR FORCE TO THE CAPACITY RATIOIN HPLC BY SCALED PARTICLE THEORY, Huaxue xuebao, 51(10), 1993, pp. 943-949
Citations number
4
Categorie Soggetti
Chemistry
Journal title
Huaxue xuebao → ACNP
ISSN journal
05677351
Volume
51
Issue
10
Year of publication
1993
Pages
943 - 949
Database
ISI
SICI code
0567-7351(1993)51:10<943:SOTEOT>2.0.ZU;2-M
Abstract
To study the effect of the intermolecular force to the capacity ratio in HPLC, the sealed particle theory and the two dimension lattice theo ry were respectively applied to study intermolecular interaction betwe en the solvent molecules and the solute molecules in the liquid phase and on the stationary phase. We also derived a quantitative relationsh ip between retention value and the intermolecular force, and the equat ion was testified by experiment.