The electrolytic processing of weak black liquor (WBL) was investigate
d in the batch mode of operation using a laboratory system. The proces
s could reduce the organic load to the recovery furnace by pre-cipitat
ing lignin from a fraction of WBL while converting up to 80% of the so
dium salts to a high-quality caustic solution. The process has the pot
ential to provide incremental capacity for an overloaded kraft recover
y system.