THE INFRARED-SPECTRUM OF PYRAZINE IN ITS METASTABLE TRIPLET-STATE - AFREE-ELECTRON-LASER STUDY

Authors
KOK P GROENEN EJJ VANAMERSFOORT PW VANDERMEER AFG
Citation
P. Kok et al., THE INFRARED-SPECTRUM OF PYRAZINE IN ITS METASTABLE TRIPLET-STATE - AFREE-ELECTRON-LASER STUDY, The Journal of chemical physics, 106(7), 1997, pp. 2984-2986
Citations number
19
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
The Journal of chemical physics → ACNP
ISSN journal
00219606
Volume
106
Issue
7
Year of publication
1997
Pages
2984 - 2986
Database
ISI
SICI code
0021-9606(1997)106:7<2984:TIOPII>2.0.ZU;2-R
Abstract
Vibrational transitions of pyrazine in the lowest triplet state have b een observed as transient changes in the intensity of the phosphoresce nce induced by the free-electron laser FELIX. All seven fundamental in frared-active modes in the range of 250 to 1600 cm(-1) have been detec ted and all vibrational frequencies are found to be considerably lower than the corresponding ones in the ground state. (C) 1997 American In stitute of Physics.