RAMAN-SPECTRA OF ENDOHEDRAL FULLERENES - LI-C60(AT)

Authors
JOSLIN CG GRAY CG GOLDMAN S YANG J POLL JD
Citation
Cg. Joslin et al., RAMAN-SPECTRA OF ENDOHEDRAL FULLERENES - LI-C60(AT), Chemical physics letters, 215(1-3), 1993, pp. 144-150
Citations number
37
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
215
Issue
1-3
Year of publication
1993
Pages
144 - 150
Database
ISI
SICI code
0009-2614(1993)215:1-3<144:ROEF-L>2.0.ZU;2-V
Abstract
The inelastic depolarized light-scattering spectrum of the endohedral metallofullerene Li+ @ C60 is calculated for frequency shifts up to 10 00 cm-1. In this species the motion of the charged inclusion within th e buckyball cage generates an induced anisotropic polarizability throu gh an interesting mechanism involving the hyperpolarizability B. The r esulting Raman spectrum is quite intense. At room temperature, hot ban ds contribute significantly to the scattering.