LASER-INDUCED FLUORESCENCE FROM THE (3)PI(U) (4(3)P,4(3)P) STATE OF ZN2

Authors
KEDZIERSKI W ATKINSON JB KRAUSE L
Citation
W. Kedzierski et al., LASER-INDUCED FLUORESCENCE FROM THE (3)PI(U) (4(3)P,4(3)P) STATE OF ZN2, Chemical physics letters, 215(1-3), 1993, pp. 185-187
Citations number
8
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
Chemical physics letters → ACNP
ISSN journal
00092614
Volume
215
Issue
1-3
Year of publication
1993
Pages
185 - 187
Database
ISI
SICI code
0009-2614(1993)215:1-3<185:LFFT((>2.0.ZU;2-0
Abstract
The 3PI(u)(4 3P, 4 3P) state of the Zn2 excimer was excited by pump-an d-probe irradiation of Zn vapor in a quartz cell. The resulting struct ured fluorescence and excitation spectra, which were recorded in the 2 70-290 nm spectral region, are interpreted as arising from 3PI(u)(4 3P , 4 3P)<-- -->3PI(g)(4 3P, 4 1S) vibronic transitions. An analysis of the vibrational structures yielded the vibrational frequencies, relati ve energies, and relative equilibrium internuclear separations for the 3PI(u) and 3PI(g) states.