Selected strains of bacteria [from the Brookhaven National Laboratory
(BNL) collection], capable of degrading heavy crude oils, were used to
treat bituminous and lignite coals. Products resulting from biochemic
al reactions among several microorganisms and different coals were exa
mined by pyrolysis gas chromatography-mass spectrometry (Py. g.c.-m.s.
), and X-ray absorption near edge structure (XANES) spectroscopy. The
results indicated considerable variations in the organic sulfur as wel
l as modifications in coal structure. Furthermore, biochemical reactio
ns involved in the microbial interactions with coals appeared to be mi
crobial species dependent.