ORBITAL CONTROL IN THE DIMERIZATION OF POLYCYCLIC AROMATIC KETONES AND QUINONES IN THE PRESENCE OF ALKALI-METAL ALCOHOLATES

Authors
TRAVEN VF SAFRONOV AI SHISHKO OF CHIBISOVA TA
Citation
Vf. Traven et al., ORBITAL CONTROL IN THE DIMERIZATION OF POLYCYCLIC AROMATIC KETONES AND QUINONES IN THE PRESENCE OF ALKALI-METAL ALCOHOLATES, Mendeleev communications, (5), 1993, pp. 216-217
Citations number
15
Categorie Soggetti
Chemistry
Journal title
Mendeleev communications → ACNP
ISSN journal
09599436
Issue
5
Year of publication
1993
Pages
216 - 217
Database
ISI
SICI code
0959-9436(1993):5<216:OCITDO>2.0.ZU;2-I
Abstract
Polycyclic aromatic ketones and quinones undergo dimerization in the p resence of alkali metal alcoholates; anion-radicals of the substrates are formed under these conditions, and the direction of dimerization d epends on the spin density in the intermediate anion-radical.