BEHAVIOR OF PT(111) IN THE PRESENCE OF THE SULFATE ANIONS IN NAOH SOLUTION

Authors
MORALLON E VAZQUEZ JL ALDAZ A ZHAI RS
Citation
E. Morallon et al., BEHAVIOR OF PT(111) IN THE PRESENCE OF THE SULFATE ANIONS IN NAOH SOLUTION, Journal of electroanalytical chemistry [1992], 360(1-2), 1993, pp. 89-100
Citations number
15
Categorie Soggetti
Electrochemistry,"Chemistry Analytical
Journal title
Journal of electroanalytical chemistry [1992]
ISSN journal
15726657 → ACNP
Volume
360
Issue
1-2
Year of publication
1993
Pages
89 - 100
Database
ISI
SICI code
Abstract
In NaOH + Na2SO4 solution a Pt(111) electrode shows a pair of broad ir reversible peaks at 0.56 V (cathodic peak) and 0.67 V (anodic peak), a fter several cycles between 0.06 and 0.89 V. These peaks can be associ ated with the formation of a surface redox couple containing adsorbed S-species that block the hydrogen adsorption-desorption process.