ORGANOMETAL LEWIS-ACIDS .52. CATIONIC PEN TACARBONYLCARBENE COMPLEXESOF MANGANESE AND RHENIUM

Authors
FRITSCH E KERSCHER T POLBORN K BECK W
Citation
E. Fritsch et al., ORGANOMETAL LEWIS-ACIDS .52. CATIONIC PEN TACARBONYLCARBENE COMPLEXESOF MANGANESE AND RHENIUM, Journal of organometallic chemistry, 460(2), 1993, pp. 30000025-30000027
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
460
Issue
2
Year of publication
1993
Pages
30000025 - 30000027
Database
ISI
SICI code
0022-328X(1993)460:2<30000025:OL.CPT>2.0.ZU;2-V
Abstract
The pentacarbonyltetrafluoroborato complexes (OC)(5)MFBF(3) react with 3-butyne-1-o1 to give the cyclic oxycarbene complexes [(OC)(5)M= COCH 2CH2CH2](BF4-)-B-+ (1:M = Mn; 2:M = Re). The structure of 2 has been d etermined by X-ray diffraction.