THE PREPARATION OF (Z)-2-LITHIO-ORTHO-STYRYLLITHIUM VIA AN ORTHO-DIRECTED LITHIATION

Authors
ASHE AJ SAVLA PM
Citation
Aj. Ashe et Pm. Savla, THE PREPARATION OF (Z)-2-LITHIO-ORTHO-STYRYLLITHIUM VIA AN ORTHO-DIRECTED LITHIATION, Journal of organometallic chemistry, 461(1-2), 1993, pp. 1-3
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
461
Issue
1-2
Year of publication
1993
Pages
1 - 3
Database
ISI
SICI code
0022-328X(1993)461:1-2<1:TPO(VA>2.0.ZU;2-O
Abstract
Lithiation of (Z)-2-lithiostyrene with t-butyllithium/TMEDA pentane le d directly to (Z)-2-lithio-ortho-styryllithium. Subsequent treatment o f this dilithio compound with difunctional electrophiles allowed the p reparation of a variety of benzo[b]heteroles.