SYNTHESIS AND CRYSTAL-STRUCTURE OF 2 TITANASILAZANES

Authors
OVCHINNIKOV YE USTINOV MV IGONIN VA STRUCHKOV YT KALIKHMAN ID VORONKOV MG
Citation
Ye. Ovchinnikov et al., SYNTHESIS AND CRYSTAL-STRUCTURE OF 2 TITANASILAZANES, Journal of organometallic chemistry, 461(1-2), 1993, pp. 75-80
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
461
Issue
1-2
Year of publication
1993
Pages
75 - 80
Database
ISI
SICI code
0022-328X(1993)461:1-2<75:SACO2T>2.0.ZU;2-N
Abstract
Interaction of TiCl4 and LiN(SiMe(3))(2) produces two titanasilazanes, whose structure is established by an X-ray study. In both structures, Ti-IV atoms are tetra-coordinated. Geometrical parameters of the cent rosymmetrical molecule of the first compound are unexceptional. In the bicyclic frame of the second complex, the bond lengths are: Ti-N 1.86 6-2.034(3), Si-N(sp(3)) 1.890(4) Angstrom.