X-RAY-ANALYSIS OF 1-PHOSPHA-1,2,3-BUTATRIENE AS A LIGAND OF CARBONYLTUNGSTEN COMPLEX

Citation
M. Yoshifuji et al., X-RAY-ANALYSIS OF 1-PHOSPHA-1,2,3-BUTATRIENE AS A LIGAND OF CARBONYLTUNGSTEN COMPLEX, Journal of organometallic chemistry, 461(1-2), 1993, pp. 81-84
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
0022328X
Volume
461
Issue
1-2
Year of publication
1993
Pages
81 - 84
Database
ISI
SICI code
0022-328X(1993)461:1-2<81:XO1AAL>2.0.ZU;2-9
Abstract
X-Ray analysis was carried out of ,4,6-tri-t-butylphenyl)-1-phospha-1, 2,3-butatriene as a ligand of pentacarbonyltungsten complex. The heter ocumulene system was found to be planar with a rod framework coordinat ing to the tungsten metal at the phosphorus atom in a sigma-type coord ination.