PREPARATION AND CHARACTERIZATION OF CATIO NIC METALLOCENE COMPLEXES [CP(2)ZR(CH3CN)(3)][ASF6](2) AND [CP(2)NBCL(2)][UF6] - LABORATORY SYNTHESIS OF UF6

Authors
SCHULZ A KLAPOTKE TM
Citation
A. Schulz et Tm. Klapotke, PREPARATION AND CHARACTERIZATION OF CATIO NIC METALLOCENE COMPLEXES [CP(2)ZR(CH3CN)(3)][ASF6](2) AND [CP(2)NBCL(2)][UF6] - LABORATORY SYNTHESIS OF UF6, Journal of organometallic chemistry, 461(1-2), 1993, pp. 91-94
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
461
Issue
1-2
Year of publication
1993
Pages
91 - 94
Database
ISI
SICI code
0022-328X(1993)461:1-2<91:PACOCN>2.0.ZU;2-W
Abstract
The five-coordinate, dicationic complex [Cp(2)Zr(CH3CN)(3)][AsF6](2) ( 1) was formed by reaction of Cp(2)ZrCl(2) and 2 equiv. of AgAsF6 in ac etonitrile. A stable, polymeric niobocenium UF6 complex, [Cp(2)NbCl(2) ][UF6] (2), was synthesized from Cp(2)NbCl(2), and UF6. A convenient l aboratory-scale synthesis of pure UF6 is reported.