THE REACTION OF[PPN][HFE(CO)(4)] WITH STYRENE IN THF - AN UNEXPECTED AND FACILE SYNTHESIS OF [PPN](2)[FE-2(CO)(8)]

Authors
BRUNET JJ NEIBECKER D SRIVASTAVA RS
Citation
Jj. Brunet et al., THE REACTION OF[PPN][HFE(CO)(4)] WITH STYRENE IN THF - AN UNEXPECTED AND FACILE SYNTHESIS OF [PPN](2)[FE-2(CO)(8)], Journal of organometallic chemistry, 461(1-2), 1993, pp. 169-172
Citations number
22
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
461
Issue
1-2
Year of publication
1993
Pages
169 - 172
Database
ISI
SICI code
0022-328X(1993)461:1-2<169:TROWSI>2.0.ZU;2-J
Abstract
The reaction of [PPN][HFe(CO)(4)] (PPN = bis(triphenylphosphine)iminiu m) with styrene in refluxing tetrahydrofuran leads to the formation of [PPN](2)[Fe-2(CO)(8)] which can be easily isolated (85% yield). The r eaction mechanism is discussed.