A SELECTIVE BAEYER-VILLIGER OXIDATION - A TOTAL SYNTHESIS OF (-)-ACETOMYCIN

Authors
ZIEGLER FE KIM HW
Citation
Fe. Ziegler et Hw. Kim, A SELECTIVE BAEYER-VILLIGER OXIDATION - A TOTAL SYNTHESIS OF (-)-ACETOMYCIN, Tetrahedron letters, 34(48), 1993, pp. 7669-7672
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
48
Year of publication
1993
Pages
7669 - 7672
Database
ISI
SICI code
0040-4039(1993)34:48<7669:ASBO-A>2.0.ZU;2-F
Abstract
A short, stereoselective synthesis of (-)-acetomycin (2) from L-threon ine is reported. The final step in the synthesis is a selective Baeyer -Villiger oxidation that discriminates between two methyl ketones.