ENZYMATIC REGIOSELECTIVE HYDROLYSIS OF PERACETYLATED REDUCING DISACCHARIDES, SPECIFICALLY AT THE ANOMERIC CENTER - INTERMEDIATES FOR THE SYNTHESIS OF OLIGOSACCHARIDES

Authors
KHAN R GROPEN L KONOWICZ PA MATULOVA M PAOLETTI S
Citation
R. Khan et al., ENZYMATIC REGIOSELECTIVE HYDROLYSIS OF PERACETYLATED REDUCING DISACCHARIDES, SPECIFICALLY AT THE ANOMERIC CENTER - INTERMEDIATES FOR THE SYNTHESIS OF OLIGOSACCHARIDES, Tetrahedron letters, 34(48), 1993, pp. 7767-7770
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
48
Year of publication
1993
Pages
7767 - 7770
Database
ISI
SICI code
0040-4039(1993)34:48<7767:ERHOPR>2.0.ZU;2-6
Abstract
An enzyme-catalysed reaction of peracetylated reducing disaccharides 1 , 4 and 6 gave exclusively either the corresponding heptaacetates 2, 5 , and 7, with the free hydroxyl group at C-1, or the hexaacetates 3 an d 8, with the hydroxyl groups at C-1,2, from the corresponding peracet ates 1 and 6.