INFLUENCE OF AMMONIA ON THE SOLUBILITY OF SODIUM-BOROHYDRIDE IN POLYETHER SOLUTIONS

Authors
BORISOV AP MAKHAEV VD
Citation
Ap. Borisov et Vd. Makhaev, INFLUENCE OF AMMONIA ON THE SOLUBILITY OF SODIUM-BOROHYDRIDE IN POLYETHER SOLUTIONS, Journal of applied chemistry of the USSR, 65(11), 1992, pp. 2157-2158
Citations number
10
Categorie Soggetti
Chemistry Applied
Journal title
Journal of applied chemistry of the USSR → ACNP
ISSN journal
0021888X
Volume
65
Issue
11
Year of publication
1992
Part
2
Pages
2157 - 2158
Database
ISI
SICI code
0021-888X(1992)65:11<2157:IOAOTS>2.0.ZU;2-T
Abstract
The solubility of sodium borohydride in 1,2-dimethoxyethane (DME) and the dimethyl ether of diethylene glycol (diglyme) is substantially inc reased in the presence of ammonia, and at room temperature it is about 16 g/100 ml of DME. The data obtained made it possible to develop a p rocedure for the crystallization of sodium borohydride from DME.