The Nahal Mishamar hoard, found in a cave in the Judean Desert in 1961
, is a key find for the study of Chalcolithic metallurgy in Israel and
the Levant. Recent analyses of Chalcolithic metalwork from sites such
as Shiqmim in Israel raised doubts about the validity of published an
alyses from the hoard. Accordingly a programme of re-analysis was esta
blished using atomic absorption spectrometry and electron probe microa
nalysis. The new analyses confirmed the doubts and showed that the met
allurgy of Nahal Mishmar was the same as that at the other sites. The
alloys used for the cast products in the hoard were generally ternary
arsenic-antimony copper alloys with up to 20% alloy content; less comm
on were compositions with arsenic and nickel. The unusual metallograph
y of these alloys is described. Some suggestions are offered as to the
mode of manufacture of the alloys.