Jet has been widely used in the past for jewellery but was just one of
a range of black lithic materials employed. When worked into small ob
jects these materials can be visually indistinguishable, yet discrimin
ation is important because of the restricted ocurrence of jet. X-ray f
luorescence (XRF) is a rapid non-destructive discriminatory technique,
but not all samples are clearly classified, and inhomogeneity may pos
e problems. A reassessment of the use of XRF is reported. Other techni
ques considered include electron spin resonance, infrared spectroscopy
, Raman spectroscopy, thermogravimetric analysis, scanning electron mi
croscopy and X-radiography. These were tested on geological materials
to define an effective methodology for archaelogical material. The rec
ommended approach is a combination of XRF and X-radiography, although
preliminary Fourier transform infrared results showed promise. The X-r
ay techniques were tested on Romano-British assemblages from Catterick
and Stanwick.