A. Grzejdziak, PROPERTIES OF THE AG(I) - 1,4,8,12-TETRAAZACYCLOPENTADECANE AND AG(I)- 1,4,7,10,13,16-HEXAAZACYCLOOCTADECANE SYSTEMS IN WATER, Polish Journal of Chemistry, 67(12), 1993, pp. 2133-2142
The protonation constants of 1,4,8,12-tetraazacyclopentadecane (TACP)
and 1,4,7,10,13,16-hexaazacyclooctadecane (HACO) in solutions with the
ionic strength of 0.1 (0.1 M KNO3) were determined pH-metrically. The
disproportionation constant of Ag(I) ions in the presence of TACP, th
e composition and the formation constant of the complex AgH2L3+ and th
e solubility product of the. salt AgH2LSO4NO3 for HACO were determined
by potentiometry.