PROPERTIES OF THE AG(I) - 1,4,8,12-TETRAAZACYCLOPENTADECANE AND AG(I)- 1,4,7,10,13,16-HEXAAZACYCLOOCTADECANE SYSTEMS IN WATER

Authors
Citation
A. Grzejdziak, PROPERTIES OF THE AG(I) - 1,4,8,12-TETRAAZACYCLOPENTADECANE AND AG(I)- 1,4,7,10,13,16-HEXAAZACYCLOOCTADECANE SYSTEMS IN WATER, Polish Journal of Chemistry, 67(12), 1993, pp. 2133-2142
Citations number
17
Categorie Soggetti
Chemistry
Journal title
ISSN journal
01375083
Volume
67
Issue
12
Year of publication
1993
Pages
2133 - 2142
Database
ISI
SICI code
0137-5083(1993)67:12<2133:POTA-1>2.0.ZU;2-Z
Abstract
The protonation constants of 1,4,8,12-tetraazacyclopentadecane (TACP) and 1,4,7,10,13,16-hexaazacyclooctadecane (HACO) in solutions with the ionic strength of 0.1 (0.1 M KNO3) were determined pH-metrically. The disproportionation constant of Ag(I) ions in the presence of TACP, th e composition and the formation constant of the complex AgH2L3+ and th e solubility product of the. salt AgH2LSO4NO3 for HACO were determined by potentiometry.