A numerical fitting method based on the deep level transient spectrosc
opy (DLTS) technique is presented. This method deals with a situation
where the standard rate window DLTS is no longer sufficient, i.e., the
assumption that the defect density N(T) is much less than the donor d
oping density N(D) is no longer valid. Digitized capacitance transient
s are numerically fit to extract the electron emission rate, defect de
nsity, and energy level. The defect center under study is EL2 in n-typ
e liquid-encapsulated Czochralski gallium arsenide. The fitting method
gives an EL2 thermal activation energy of 0.76 eV, different from the
0.82 eV obtained by standard DLTS, which only examines the maximum em
ission conditions. The advantages, as well as the limitations, of this
fitting method are discussed.