A crucial need exists to analyze the composition of materials nondestr
uctively. Energy-dispersive spectrometers are widely used to perform t
his function, but their performance is limited by the energy resolutio
n of the detector, typically 150 eV for Si(Li) at 6 keV. Calorimeters
and tunnel junctions offer more than an order of magnitude improvement
in energy resolution, with the prospect of vast improvements in perfo
rmance for quantitative analysis. We present an analysis of the critic
al issues pertaining to the use of calorimeters for quantitative mater
ials analysis, and show that significant performance advantages may be
realized with the energy resolutions already achieved. We also descri
be other x-ray analysis methods for determining the chemical state of
the material to be studied, which also may benefit from calorimeter te
chnology.