COMPUTER-SIMULATION OF CHIRAL LIQUID-CRYSTAL PHASES .2. THE USE OF TWISTED BOUNDARY-CONDITIONS

Citation
R. Memmer et al., COMPUTER-SIMULATION OF CHIRAL LIQUID-CRYSTAL PHASES .2. THE USE OF TWISTED BOUNDARY-CONDITIONS, Berichte der Bunsengesellschaft fur Physikalische Chemie, 97(10), 1993, pp. 1193-1199
Citations number
14
Categorie Soggetti
Chemistry Physical
Journal title
Berichte der Bunsengesellschaft fur Physikalische Chemie
ISSN journal
00059021 → ACNP
Volume
97
Issue
10
Year of publication
1993
Pages
1193 - 1199
Database
ISI
SICI code
0005-9021(1993)97:10<1193:COCLP.>2.0.ZU;2-E
Abstract
Using the Monte Carlo technique, we study an ensemble of N = 256 parti cles interacting via a chiral modified Gay-Berne potential introduced in part 1. We introduce twisted boundary conditions which allow the fo rmation of helical phases with lower potential energy and a larger pit ch in comparison with the results of simulations using cubic periodic boundary conditions. The amount of chiral and achiral energy contribut ions to the total potential energy are discussed for the obtained chol esteric, helical smectic and blue phases.