STEREOCHEMISTRY OF TRANSITION-STATES AND MECHANISMS OF CHEMICAL-REACTIONS ON SILICA SURFACE

Authors
GORLOV YI
Citation
Yi. Gorlov, STEREOCHEMISTRY OF TRANSITION-STATES AND MECHANISMS OF CHEMICAL-REACTIONS ON SILICA SURFACE, Reaction kinetics and catalysis letters, 50(1-2), 1993, pp. 89-96
Citations number
4
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
50
Issue
1-2
Year of publication
1993
Pages
89 - 96
Database
ISI
SICI code
0133-1736(1993)50:1-2<89:SOTAMO>2.0.ZU;2-#
Abstract
The activation energy of substitution and bond cleavage reactions of s iloxane derivatives on silica surfaces is discussed considering the st ereochemistry of the transition state. General concepts are developed and utilized in predicting reactivity trends for reactions occurring o n the silica surface.