POLARIZATION FOURIER-TRANSFORM INFRARED-SPECTROSCOPY ON IONIC SINGLE-CRYSTAL SURFACES - DAVYDOV SPLITTINGS, ADSORBATED STRUCTURES AND 2D-PHASE TRANSITIONS ON NACL(100) AND MGO(100)

Citation
J. Heidberg et al., POLARIZATION FOURIER-TRANSFORM INFRARED-SPECTROSCOPY ON IONIC SINGLE-CRYSTAL SURFACES - DAVYDOV SPLITTINGS, ADSORBATED STRUCTURES AND 2D-PHASE TRANSITIONS ON NACL(100) AND MGO(100), Reaction kinetics and catalysis letters, 50(1-2), 1993, pp. 123-129
Citations number
14
Categorie Soggetti
Chemistry Physical
ISSN journal
01331736
Volume
50
Issue
1-2
Year of publication
1993
Pages
123 - 129
Database
ISI
SICI code
0133-1736(1993)50:1-2<123:PFIOIS>2.0.ZU;2-P
Abstract
Polarized infrared spectra of adsorbates on NaCl(100) and MgO(100) sin gle crystal cleavage planes reveal Davydov splittings, structures with adsorbate orientations and/or 2D-phase transitions, in concert with d iffraction studies. CO2 on NaCl shows the sharpest adsorbate spectra k nown (delta nuBAR < 0.04 cm-1).