INTERACTION OF TRIMETHYLCHLOROSILANE WITH SILANOL GROUPS SILICA SURFACE IN THE PRESENCE OF AMINES

Authors
PAKHLOV EM GUNKO VM VORONIN EF
Citation
Em. Pakhlov et al., INTERACTION OF TRIMETHYLCHLOROSILANE WITH SILANOL GROUPS SILICA SURFACE IN THE PRESENCE OF AMINES, Reaction kinetics and catalysis letters, 50(1-2), 1993, pp. 305-310
Citations number
7
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
50
Issue
1-2
Year of publication
1993
Pages
305 - 310
Database
ISI
SICI code
0133-1736(1993)50:1-2<305:IOTWSG>2.0.ZU;2-Z
Abstract
Experimental and quantum chemical studies of ClSi(CH3)3 interactions w ith =SiOH groups catalyzed by amines were carried out using aerosil sm aples. The catalytic effects are due to the enthalpy factor of rate co nstants through transition state stabilization by NR3.