DETERMINATION OF NICKEL IN BIOLOGICAL SAMPLES PREPARED BY MICROWAVE DISSOLUTION USING ELECTROTHERMAL ATOMIC-ABSORPTION SPECTROMETRY AFTER EXTRACTION WITH 1,5-BIS[PHENYL-(2-PYRIDYL)METHYLENE] THIOCARBONHYDRAZIDE

Authors
ALONSO EV PAVON JMC DETORRES AG CORDERO MTS
Citation
Ev. Alonso et al., DETERMINATION OF NICKEL IN BIOLOGICAL SAMPLES PREPARED BY MICROWAVE DISSOLUTION USING ELECTROTHERMAL ATOMIC-ABSORPTION SPECTROMETRY AFTER EXTRACTION WITH 1,5-BIS[PHENYL-(2-PYRIDYL)METHYLENE] THIOCARBONHYDRAZIDE, Analytica chimica acta, 283(1), 1993, pp. 224-229
Citations number
7
Categorie Soggetti
Chemistry Analytical
Journal title
Analytica chimica acta → ACNP
ISSN journal
00032670
Volume
283
Issue
1
Year of publication
1993
Pages
224 - 229
Database
ISI
SICI code
0003-2670(1993)283:1<224:DONIBS>2.0.ZU;2-T
Abstract
An electrothermal atomization atomic absorption spectrometric method f or the determination of traces of nickel after extraction of the metal into methyl isobutyl ketone containing 1,5-bis[phenyl(2-pyridyl)methy lene) thiocarbonhydrazide is suggested. The chief advantage of the met hod lies in its maximum allowable aqueous-to-organic phase volume rati o of 37. The method was applied to the determination of nickel in vari ous biological tissues, serum and human urine.