SYNTHESIS AND COPOLYMERIZATION BEHAVIOR OF METHACRYLATE DIMERS

Citation
Kj. Abbey et al., SYNTHESIS AND COPOLYMERIZATION BEHAVIOR OF METHACRYLATE DIMERS, Journal of polymer science. Part A, Polymer chemistry, 31(13), 1993, pp. 3417-3424
Citations number
16
Categorie Soggetti
Polymer Sciences
ISSN journal
0887624X
Volume
31
Issue
13
Year of publication
1993
Pages
3417 - 3424
Database
ISI
SICI code
0887-624X(1993)31:13<3417:SACBOM>2.0.ZU;2-X
Abstract
Methacrylic ester-based dimers and oligomers were synthesized using a metal-based catalytic chain transfer agent. Conditions were employed w hich maximized the yield of unsaturated dimers, and the copolymerizati on behavior of these dimers was investigated. The molecular weight and polymer yield were found to decrease with increasing dimer concentrat ion in the copolymerization feeds. (C) 1993 John Wiley & Sons, Inc.