The selective cleavage of carbon-hydrogen bonds in organic compounds i
s a critical step in many organic syntheses, and is particularly impor
tant in the conversion of hydrocarbons to useful organic compounds. An
organometallic ruthenium complex can cleave C-H bonds in a variety of
aromatic systems, leading to addition to alkenes by C-C bond formatio
n. The catalyst operates with a degree of efficiency, selectivity and
generality that will make it extremely valuable in organic synthesis.