EFFICIENT CATALYTIC ADDITION OF AROMATIC CARBON-HYDROGEN BONDS TO OLEFINS

Citation
S. Murai et al., EFFICIENT CATALYTIC ADDITION OF AROMATIC CARBON-HYDROGEN BONDS TO OLEFINS, Nature, 366(6455), 1993, pp. 529-531
Citations number
18
Categorie Soggetti
Multidisciplinary Sciences
Journal title
NatureACNP
ISSN journal
00280836
Volume
366
Issue
6455
Year of publication
1993
Pages
529 - 531
Database
ISI
SICI code
0028-0836(1993)366:6455<529:ECAOAC>2.0.ZU;2-S
Abstract
The selective cleavage of carbon-hydrogen bonds in organic compounds i s a critical step in many organic syntheses, and is particularly impor tant in the conversion of hydrocarbons to useful organic compounds. An organometallic ruthenium complex can cleave C-H bonds in a variety of aromatic systems, leading to addition to alkenes by C-C bond formatio n. The catalyst operates with a degree of efficiency, selectivity and generality that will make it extremely valuable in organic synthesis.