THE REPEATABILITY OF THE QUANTITATIVE-ANALYSIS IN ELECTROCHROMATOGRAPHY

Citation
P. Coufal et al., THE REPEATABILITY OF THE QUANTITATIVE-ANALYSIS IN ELECTROCHROMATOGRAPHY, Journal of liquid chromatography, 16(17), 1993, pp. 3623-3652
Citations number
19
Categorie Soggetti
Chemistry Analytical
ISSN journal
01483919
Volume
16
Issue
17
Year of publication
1993
Pages
3623 - 3652
Database
ISI
SICI code
0148-3919(1993)16:17<3623:TROTQI>2.0.ZU;2-7
Abstract
The effect of a number of injection and separation parameters on the r epeatability of quantitative analyses on a home-constructed instrument for electrochromatography was studied. The performance of electrokine tic and hydrostatic sample injection methods was compared. Peak area a nd peak height values were applied as the evaluation parameters. The b est quantitative repeatability for charged and uncharged compounds, ob tained in this study was in the range of 1 % to 5 % of relative standa rd deviation.