Ab. Kukushkin, AN EQUATION FOR RESONANCE-RADIATION TRANSFER IN A HEAVY-ATOM GAS INJECTED INTO A RAREFIED ATMOSPHERE, Journal of quantitative spectroscopy & radiative transfer, 50(5), 1993, pp. 541-549
An analytic description is given for the collision-perturbed expansion
(CPE) of the neutral component of a heavy-atom gas injected into a ra
refied atmosphere, and for the velocity-dependent transport cross-sect
ion for barium-oxygen collisions. A closed equation is formulated for
the transport of linearly-polarized resonance radiation in a non-Maxwe
llian gas composed of two-level, zero-spin atoms. Analytic results are
obtained for the local values of the absorption coefficient and photo
n redistribution function, which extend the respective quantities for
Doppler broadening of the spectral lines in a Maxwellian gas to the ca
se of the CPE gas. It is shown that even for almost free expansion of
the artificial cloud, the spectral line width of injected heavy atoms
may be determined by non-equilibrium Doppler-type broadening, caused b
y their collisions with atmospheric atoms. The results may be generali
zed to the case of multilevel kinetics, arbitrary photon polarization
and atomic spin.