LI-7 SOLID-STATE NMR-STUDY OF A TMEDA COMPLEX OF TRIMETHYLSILYLCYCLOPENTADIENYLLITHIUM

Authors
PIETRASS T BURKERT PK
Citation
T. Pietrass et Pk. Burkert, LI-7 SOLID-STATE NMR-STUDY OF A TMEDA COMPLEX OF TRIMETHYLSILYLCYCLOPENTADIENYLLITHIUM, Zeitschrift fur Naturforschung. B, A journal of chemical sciences, 48(11), 1993, pp. 1555-1557
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Zeitschrift fur Naturforschung. B, A journal of chemical sciences → ACNP
ISSN journal
09320776
Volume
48
Issue
11
Year of publication
1993
Pages
1555 - 1557
Database
ISI
SICI code
0932-0776(1993)48:11<1555:LSNOAT>2.0.ZU;2-5
Abstract
Li-7 solid state NMR spectroscopy of ylenediamine-trimethylsilylcyclop entadienyllithium yielded an unusually large quadrupole coupling const ant, that decreases with increasing temperature (188-165 kHz in the te mperature range 210-335 K). Structural features, known from the X-ray analysis, are compared with the NMR results.