We show from transport investigations that Ge doped GaAs can be either
semimetallic or semiconducting depending on hydrostatic pressure and
previous sample illumination. This property results from a unique cros
sover of two states of the Ge donor in GaAs in their energetic positio
n under pressure. The experimental results obtained make it possible t
o identify the nature of these Ge-donor states: The drastic enhancemen
t of the electron mobility after illumination is taken as evidence of
the electron transfer from the two-electron DX- state to a neutral, lo
calized, and unrelaxed state of the Ge donor.