N-(DIPHENYLPHOSPHINOTHIOYL)HYDROXYLAMINE TRANSPOSITION OF O AND S IN ITS O-BENZOYL DERIVATIVE

Authors
HARGER MJP
Citation
Mjp. Harger, N-(DIPHENYLPHOSPHINOTHIOYL)HYDROXYLAMINE TRANSPOSITION OF O AND S IN ITS O-BENZOYL DERIVATIVE, Tetrahedron letters, 34(49), 1993, pp. 7947-7948
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
34
Issue
49
Year of publication
1993
Pages
7947 - 7948
Database
ISI
SICI code
0040-4039(1993)34:49<7947:NTOOAS>2.0.ZU;2-Y
Abstract
N-(Diphenylphosphinothioyl)hydroxylamine has been prepared from Ph(2)P (S)Cl using H(2)NOSiMe(3). The derivative Ph(2)P(S)NHOCOPh rearranges to Ph(2)P(O)NHSCOPh with base; this transposition of O and S seems to require a 3-membered ring comprising P, S and N atoms.