RESOLUTION OF ENANTIOMERS OF CIS-FUSED AND TRANS-FUSED C-60-ENONE [2+2] PHOTOADDUCTS

Authors
WILSON SR WU YH KAPRINIDIS NA SCHUSTER DI WELCH CJ
Citation
Sr. Wilson et al., RESOLUTION OF ENANTIOMERS OF CIS-FUSED AND TRANS-FUSED C-60-ENONE [2+2] PHOTOADDUCTS, Journal of organic chemistry, 58(24), 1993, pp. 6548-6549
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
58
Issue
24
Year of publication
1993
Pages
6548 - 6549
Database
ISI
SICI code
0022-3263(1993)58:24<6548:ROEOCA>2.0.ZU;2-3
Abstract
Enantiomers of the mixture of cis and trans photocycloadducts of C60 a nd 3-methylcyclohexenone were separated by HPLC on the chiral stationa ry phase (S,S)-Whelk-O; chiroptical properties indicate that the fulle rene moiety in the strained trans cycloadducts has a skewed pi-system with local C2 symmetry.