Nuclear magnetic resonance relaxation measurements were used to identi
fy different characteristic porosity domains in soil and aquifer mater
ials. The porosity distribution can be inferred from these measurement
s by a regularization method applicable to any nuclear magnetic resona
nce (NMR) relaxation, or by an analytic method applicable only to mult
iexponential relaxations (D'Orazio et al., 1989). The porosity distrib
ution obtained from NMR relaxation measurements strongly depends on th
e pore shape factor. For the Borden aquifer material, both the regular
ized and the analytic pore size distribution obtained from NMR relaxat
ion measurements are consistent with those obtained by Ball et al. (19
90) using Hg porosimetry and N2 adsorption. For the Eustis and the Web
ster soils, the measured porosity domains are qualitatively consistent
with those expected based on their respective composition. Our findin
gs suggest that due to the long time required to saturate fine pores,
NMR measurements of porosity distribution that are collected at short
saturation times are biased toward larger pore sizes.