Electrophoretic light scattering was used to study the electrophoretic
mobility of polylysine as a function of pH in both NaCl and phosphate
buffer solutions at an ionic strength of 0.01 M. Results are interpre
ted in terms of the counterion condensation theory. It is concluded th
at this theory may be qualitatively correct, but its application to th
e calculation of the electrophoretic mobility is not yet quantitativel
y satisfied.