The photoabsorption spectra of nano-crystalline silicon (nc-Si:H) film
s were measured by means of constant photoconductivity method. We inve
stigated the changes of absorption spectra with the increasing of crys
tallinity as the deposited films are amorphous, microcrystalline and n
ano-crystalline. We found that in nc-Si: H the transition processess i
n the interfacial region between the grains predominate the whole rang
e of the absorption spectra. We related the phenomenon to the structur
al changes in the material.