THE RING-OPENING METATHESIS POLYMERIZATION OF (PLUS-OR-MINUS)-5-ENDO-METHOXYNORBORN-2-ENE - MICROSTRUCTURE OF THE POLYMERS

Authors
IVIN KJ LAM LM ROONEY JJ
Citation
Kj. Ivin et al., THE RING-OPENING METATHESIS POLYMERIZATION OF (PLUS-OR-MINUS)-5-ENDO-METHOXYNORBORN-2-ENE - MICROSTRUCTURE OF THE POLYMERS, Die Makromolekulare Chemie, 194(12), 1993, pp. 3493-3497
Citations number
5
Categorie Soggetti
Polymer Sciences
Journal title
Die Makromolekulare Chemie → ACNP
ISSN journal
0025116X
Volume
194
Issue
12
Year of publication
1993
Pages
3493 - 3497
Database
ISI
SICI code
0025-116X(1993)194:12<3493:TRMPO(>2.0.ZU;2-0
Abstract
The title monomer (+/-)-5-endo-methoxynorborn-2-ene ((+/-)-5-endo-meth oxybicyclo[2.2.1]hept-2-ene, 1) was polymerized by Ru-, W-, Ir-, Re- a nd Mo-based metathesis catalysts to yield polymers with cis contents r anging from 10% to 48%. An assignment of the C-13 NMR spectra was made . No significant head-tail bias was observed and no splitting due to t acticity could be positively identified.