SYNTHESIS AND CHARACTERIZATION OF A BINUCLEAR IRON-MU-PEROXO COMPLEX OF A TETRAAZA MACROCYCLIC LIGAND

Authors
LEVY NM STADLER E MANGRICH AS MELO MAC DRAGO V
Citation
Nm. Levy et al., SYNTHESIS AND CHARACTERIZATION OF A BINUCLEAR IRON-MU-PEROXO COMPLEX OF A TETRAAZA MACROCYCLIC LIGAND, Transition metal chemistry, 18(6), 1993, pp. 613-618
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
18
Issue
6
Year of publication
1993
Pages
613 - 618
Database
ISI
SICI code
0340-4285(1993)18:6<613:SACOAB>2.0.ZU;2-8
Abstract
The dimerization of complex (1), [Fe(TIM)(H2O)(2)](2+) tetramethyl-1,4 ,8,11-tetraazacyclotetradeca-1,3,8, 10-tetraene) in aerated aqueous so lution results in formation of the binuclear complex (2), [(H2O)(TIM)F e-O-O-Fe(TIM)(H2O])(4+). Complex (2) has been characterized by element al analysis, spectroscopy and electrochemical data.