SYNTHESIS OF FUNCTIONALIZED LONG-CHAIN PERFLUOROALKANES FROM METHYL HALODIFLUOROACETATES - A PROCESS OF DIFLUOROCARBENE INSERTION INTO COPPER-CARBON BONDS

Authors
SU DB DUAN JX YU AJ CHEN QY
Citation
Db. Su et al., SYNTHESIS OF FUNCTIONALIZED LONG-CHAIN PERFLUOROALKANES FROM METHYL HALODIFLUOROACETATES - A PROCESS OF DIFLUOROCARBENE INSERTION INTO COPPER-CARBON BONDS, Journal of fluorine chemistry, 65(1-2), 1993, pp. 11-14
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
65
Issue
1-2
Year of publication
1993
Pages
11 - 14
Database
ISI
SICI code
0022-1139(1993)65:1-2<11:SOFLPF>2.0.ZU;2-V
Abstract
Treatment of XCF(2)CO(2)Me (X=Cl, Br) with organic halides in the pres ence of KF and catalytic amounts of CuI at 80-120 degrees C for 3-8 h in DMF gave long-chain perfluoroalkylated compounds which are consider ed to be former by the insertions of CF :(2) into carbon-copper bonds.