3,3,3-TRIFLUORO-2-ISOCYANOPROPIONATES, NEW VERSATILE BUILDING-BLOCKS FOR THE INTRODUCTION OF TRIFLUOROMETHYL GROUPS INTO ORGANIC-MOLECULES

Authors
BURGER K SCHIERLINGER C MUTZE K
Citation
K. Burger et al., 3,3,3-TRIFLUORO-2-ISOCYANOPROPIONATES, NEW VERSATILE BUILDING-BLOCKS FOR THE INTRODUCTION OF TRIFLUOROMETHYL GROUPS INTO ORGANIC-MOLECULES, Journal of fluorine chemistry, 65(1-2), 1993, pp. 149-152
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
65
Issue
1-2
Year of publication
1993
Pages
149 - 152
Database
ISI
SICI code
0022-1139(1993)65:1-2<149:3NVBF>2.0.ZU;2-T
Abstract
alpha-Trifluoromethyl-substituted alpha-amino acid esters 1 give N-for myl alpha-trifluoromethyl alpha-amino acid esters 2 on reaction with f ormic acid/acetic anhydride. 3,3,3-Trifluoro-2-isocyanopropionates 3 a re obtained from 2 upon treatment with diphosgene/triethylamine.