KINETIC-BEHAVIOR OF ADDITION-REACTIONS TO [60]FULLERENE

Authors
GECKELER KE ARSALANI N
Citation
Ke. Geckeler et N. Arsalani, KINETIC-BEHAVIOR OF ADDITION-REACTIONS TO [60]FULLERENE, Fullerene science and technology, 5(1), 1997, pp. 127-135
Citations number
20
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical","Material Science
Journal title
Fullerene science and technology → ACNP
ISSN journal
1064122X
Volume
5
Issue
1
Year of publication
1997
Pages
127 - 135
Database
ISI
SICI code
1064-122X(1997)5:1<127:KOAT[>2.0.ZU;2-A
Abstract
The addition reactions of [60]fullerene to benzyl amine and anthracene were studied by using spectrophotometry. The kinetic measurements sho w minima if the absorbance at a wavelength of 595 nm is plotted versus time. The minima obtained from the spectrophotometric kinetic measure ments can be attributed to the formation of intermediates of C-60 due to the single-electron transfer mechanism for the amine addition and e lectron delocalization processes for the concerted [2+4]cyclo-addition .