PREPARATION AND CHARACTERIZATION OF TERNARY ND-PR-SB ALLOYS

Citation
P. Riani et al., PREPARATION AND CHARACTERIZATION OF TERNARY ND-PR-SB ALLOYS, Journal of alloys and compounds, 202, 1993, pp. 120000011-120000014
Citations number
26
Categorie Soggetti
Chemistry Physical","Metallurgy & Mining","Material Science
ISSN journal
09258388
Volume
202
Year of publication
1993
Pages
120000011 - 120000014
Database
ISI
SICI code
0925-8388(1993)202:<120000011:PACOTN>2.0.ZU;2-O
Abstract
Ternary Nd-Pr-Sb alloys were studied using X-ray powder diffraction an d optical and electron microscopy. (Nd, Pr)2Sb (tI12 - La2Sb type), (N d, Pr)4Sb3 (cI28 - anti-Th3P4 type), (Nd, Pr)Sb (cF8 - NaCl type) and (Nd, Pr)Sb2 (oC24 - SmSb2 type) show complete solubility between Nd an d Pr. The variation of the lattice parameters as a function of the Nd to Pr ratio was determined. In addition, the alloy Nd0.475Pr0.475Sb0.0 5 was investigated by differential thermal analysis (DTA). The results obtained confirm a previous thermodynamic prediction of the Nd-Pr-Sb phase equilibria.