M. Sahimi, FRACTAL AND SUPERDIFFUSIVE TRANSPORT AND HYDRODYNAMIC DISPERSION IN HETEROGENEOUS POROUS-MEDIA, Transport in porous media, 13(1), 1993, pp. 3-40
We review and discuss diffusion and hydrodynamic dispersion in a heter
ogeneous porous medium. Two types of heterogeneities are considered. O
ne is percolation disorder in which a fraction of the pores do not all
ow transport to take place at all. In the other type, the permeabiliti
es of various regions of the pore space are fractally distributed with
long-range correlations. Both systems give rise to unusual transport
in which the mean square displacement [r2(t)] of a particle grows nonl
inearly with time. Depending on the heterogeneities and the mechanism
of diffusion and disperison, we may have fractal transport in which [r
2] grows slower than linearly with time, or superdiffusive transport i
n which [r2] grows faster than linearly with time. We show that percol
ation models can give rise to both types of transport with scale-depen
dent transport coefficients such as diffusivity and dispersion coeffic
ients, which are consistent with many experimental observations.