Jh. Cushman et Tr. Ginn, NONLOCAL DISPERSION IN MEDIA WITH CONTINUOUSLY EVOLVING SCALES OF HETEROGENEITY, Transport in porous media, 13(1), 1993, pp. 123-138
General nonlocal diffusive and dispersive transport theories are deriv
ed from molecular hydrodynamics and associated theories of statistical
mechanical correlation functions, using the memory function formalism
and the projection operator method. Expansion approximations of a spa
tially and temporally nonlocal convective-dispersive equation are intr
oduced to derive linearized inverse solutions for transport coefficien
ts. The development is focused on deriving relations between the frequ
ency- and wave-vector-dependent dispersion tensor and measurable quant
ities. The resulting theory is applicable to porous media of fractal c
haracter.