FEATURES OF THE MODIFICATION OF A CATALYTIC-SYSTEM BASED ON A RHCL3-CENTER-DOT-POLYELECTROLYTE COMPLEX WITH ORGANOPHOSPHOROUS(III) LIGANDS IN THE HYDROFORMYLATION OF OLEFINS UNDER 2-PHASE CONDITIONS

Authors
SHARIKOVA MV MARKOVA NA KOLESNICHENKO NV TELESHEV AT SLIVINSKII YV VYTNOVA LA
Citation
Mv. Sharikova et al., FEATURES OF THE MODIFICATION OF A CATALYTIC-SYSTEM BASED ON A RHCL3-CENTER-DOT-POLYELECTROLYTE COMPLEX WITH ORGANOPHOSPHOROUS(III) LIGANDS IN THE HYDROFORMYLATION OF OLEFINS UNDER 2-PHASE CONDITIONS, Petroleum chemistry, 36(5), 1996, pp. 423-427
Citations number
5
Categorie Soggetti
Energy & Fuels","Engineering, Chemical","Engineering, Petroleum
Journal title
Petroleum chemistry → ACNP
ISSN journal
09655441
Volume
36
Issue
5
Year of publication
1996
Pages
423 - 427
Database
ISI
SICI code
0965-5441(1996)36:5<423:FOTMOA>2.0.ZU;2-V
Abstract
An investigation has been made of the influence of the nature of the o rganophosphorus ligands and the P/Rh molar ratio on the catalytic prop erties of the RhCl3 . PEI system for the hydroformylation of but-2-ene s under two-phase conditions. It has been shown that the best properti es are exhibited by a system based on RhCl3 . PEI and modified with et riolphosphite (P/Rh = 2), which makes it possible to carry out stable hydroformylation with high activity and selectivity. (C) 1997 Elsevier Science Ltd.