N. Andritsos et al., CALCIUM-CARBONATE DEPOSIT FORMATION UNDER ISOTHERMAL CONDITIONS, Canadian journal of chemical engineering, 74(6), 1996, pp. 911-919
Scale formation of calcium carbonate on tube walls is studied in a onc
e-through flow system under isothermal conditions. The effects of supe
rsaturation ratio, flow velocity and liquid temperature on the deposit
ion rates are investigated. For relatively small supersaturation ratio
s (in the range 3.5 to 8) the deposition rate tends to increase with i
ncreasing supersaturation. For higher fluid supersaturations with resp
ect to calcium carbonate, the deposition rates remain roughly constant
but they are influenced strongly by the fluid velocity. This dependen
ce of the deposition rate on fluid flow suggests a mass transfer-contr
olled process.