ON THE STRUCTURAL ANALYTICAL APPLICATION OF ANOMALOUS MULTIPLETS IN OFF-RESONANCE DECOUPLED C-13 NMR-SPECTRA OF -CH=CH-FRAGMENTS

Authors
RADEGLIA R POLESCHNER H THEIL F
Citation
R. Radeglia et al., ON THE STRUCTURAL ANALYTICAL APPLICATION OF ANOMALOUS MULTIPLETS IN OFF-RESONANCE DECOUPLED C-13 NMR-SPECTRA OF -CH=CH-FRAGMENTS, Journal fur praktische Chemie, Chemiker-Zeitung, 335(8), 1993, pp. 673-679
Citations number
20
Categorie Soggetti
Chemistry,"Chemistry Applied
Journal title
Journal fur praktische Chemie, Chemiker-Zeitung → ACNP
ISSN journal
09411216
Volume
335
Issue
8
Year of publication
1993
Pages
673 - 679
Database
ISI
SICI code
0941-1216(1993)335:8<673:OTSAAO>2.0.ZU;2-4
Abstract
The theoretical background of ''anomalous'' splitting of signals of mo lcular fragments -CH=CH- in off-resonance decoupled C-13 NMR spectra i s described. The use of these splitting phenomena on the determination of vicinal H,H and geminal C,H coupling constants is demonstrated usi ng simple examples. The possibilities to determine the configuration o f double bonds are shown by other examples from the field of natural c onstituents chemistry.