G. Burrafato et F. Miano, DETERMINATION OF THE CATION-EXCHANGE CAPACITY OF CLAYS BY SURFACE-TENSION MEASUREMENTS, Clay Minerals, 28(3), 1993, pp. 475-481
The cation exchange capacity (CEC) of clay minerals has been determine
d by titration of aqueous suspension of clays with hexadecylpyridinium
chloride, monitored using surface tension measurements. In order to m
ake the method suitable for an accurate analysis of the CEC of the cla
ys in drilling fluids or in soils, some parameters affecting the CEC d
etermination (e.g. the presence of carboxymethylcellulose, mixing time
and measurement device) have been investigated.